ir离子对Carbocatio
碳正离子No
classicalcarbocatio
非经典碳正离子Carba
io
碳负离子Maskedcarba
io
掩蔽碳负离子Carbe
oid卡宾体Carbe
eCarbe
e卡宾Nitre
e氮宾Carbi
e碳炔Electrophilicadditio
亲电加成Electrophile亲电体Diaxialadditio
双直键加成Markov
ikov’srube马尔科夫尼科规则A
tiA
tiMarkov
ikovadditio
反马氏加成Michaeladditio
迈克尔加成Substitutio
取代Electrophilicsubstitutio
亲电取代Additio
elimi
atio
Additio
elimi
atio
mecha
ism加成消除机理substituElectrophilicaromaticsubstitutio
亲电芳香取代Electro
tra
sfer电子转移Electro
Electro
do
ati
ggroup给电子基团Electro
Electro
Withdrawi
ggroup吸电子基团Deactivati
ggroup钝化基团Ori
e
tatio
取向OrthoOrthoparadirecti
ggroup邻对位定位基Metadirecti
ggroup间位定位基Orthoeffect邻位效应Partialratefactor分速度系数Nucleophilicreactio
亲核反应
4
fI
ter
alretur
内返Nucleophilicity亲核体Nucleophilicity亲核性αeffectα效应Backsideattack背面进攻I
versio
反转Umbrellaeffect伞效应PushPushpulleffect推拉效应Leavi
ggroup离去基团Electrofuge离电体Nucleofuge离核体PhasePhasetra
sfercatalysis相转移催化Neighbori
ggroupparticipatio
邻基基参与Neighbori
gproupassista
cea
chimericassista
ce邻助作用Neighbori
ggroupeffect邻基效应Apofacialreactio
反面反应Briddgeheaddisplaceme
t桥头取代Arylactio
芳正离子Be
zy
e苯炔Zaitsevrule札依采夫规则A
tiA
tiZaitsevorie
tatio
反札依采夫定向Hofma
’srule霍夫曼规则Bredtrule布雷特规则I
itiatio
引发A
io
iccleavage负离子裂解Partialbo
dfixatio
键的部分固定化02．有机化学反应02．3有机化学反应Alkylatio
烷基化Calkylatio
C烷基化Oalkylatio
O烷基化Nalkylatio
N烷基化硅烷Silylatio
硅烷基化Exhaustivemethylatio
彻底甲基化Secoalkylatio
断裂烷基化Demethylatio
脱甲基化Ethylatio
乙基化
Arylatio
芳基化Acylatio
酰化Formylatio
甲酰化Carbalkoxylatio
烷氧羰基化Carboamidatio
氨羰基化Carboxylatio
羧基化氨基化Ami
atio
氨基化Bisami
atio
双氨基化Ci
esubstitutio
移位取代Tra
sami
atio
氨基交换Hydroxylatio
羟基化acyloxyatio
酰氧基化Decarboxylative
itratio
脱羧卤化Allylichaloge
atio
烯丙型卤化Dehaloge
atio
脱卤Nitratio
硝化Decarboxylative
itratio
脱羧硝化Nitrosatio
亚硝化Sulfo
atio
Sulfo
atio
磺化Chlorosulfo
atio
氯磺酰化Desulfo
atio
脱磺酸基Sulfe
ylatio
亚磺酰化Sulfo
ylatio
磺酰化Chlorosulfe
atio
氯亚磺酰化Chlorocarbo
ylatio
氯羰基化Diazotizatio
重氮化Diazotra
sfer重氮基转移Coupli
greactio
偶联反应Diazo
iumcoupli
g重氮偶联CrossCrosscoupli
greactio
r