icco
sta
t介电常数Solvatedelectro
溶剂化电子AcidAcidbasecatalyzedreactio
酸碱催化反应Co
jugatebase共轭酸Co
jugatebase共轭碱
ody
amicThermody
amicacidity热力学酸度Ki
eticacidity动力学酸度do
ofElectro
do
ofacceptorcomplex电子给EDAcomplex电子给体受体络合物Host主体Guest客体Primaryisotopeeffect一级同位素效应Seco
daryisotopeeffect二级同位数效应I
verseisotopeeffect逆同位素效应Ki
eticco
trol动力学控制Thermody
amicco
trol热力学控制Substrate底物I
termediate中间体Reactivei
termediate活泼中间体Microscopicreversibility微观可逆性Hammo
dpostulate哈蒙德假说Li
earfreee
ergy线性自由能No
No
bo
dedi
teractio
非键相互作用Torsio
aleffect扭转效应Pitzerstrai
皮策张力Restrictedrotatio
阻碍旋转Eclipsi
gEclipsi
geffect重叠效应Eclipsi
gstrai
重叠张力SmallSmalla
glestrai
小角张力Largea
glestrai
大角张力Tra
sa
ulari
teractio
跨环相互作用Tra
sa
ularstrai
跨环张力Istrai
内张力Fstrai
前张力Bstrai
后张力A
omericeffect端基异构效应Walde
i
versio
瓦尔登反转Racemizatio
外消旋化Isoi
versio
等反转Isoracemizatio
等消旋纯手性Homochiral纯手性的Mecha
ism机理
3
fU
imolecular
ucleophilic单分子亲核取代subBimolecular
ucleophilicsubstitutio
双分子亲核取代substiBimolecular
ucleophilicsubstirearra
getutio
withallylicrearra
geme双分子亲核取代（含烯丙型重排）
t双分子亲核取代（含烯丙型重排）
ucleophilicsubstiruI
ter
al
ucleophilicsubstirutio
分子内亲核取代substituAromatic
ucleophilicsubstitutio
芳香亲核取代subU
imolecularelectrophilicsubstitutio
单分子亲电取代Bimolecularelectrophilicsubstitutio
双分子亲电取代Nucleophileu
imolecuNucleophileassistedu
imolecularelectrophilicsubstitutio
亲核体协助单分子亲电取代U
imolecularU
imolecularelimi
atio
单分子消除Bimolecularelimi
atio
双分子消除U
imolecularelimi
atio
throughtheco
jugatebase单分子共轭碱消除Bimolecularelimi
atio
throughtheco
jugatebase双分子共轭碱消除Bimolecularelimi
atio
withformatio
ofacarbo
ylgroup双分子羰基形成消除U
imolecularacidU
imolecularacidcatalyzedacyloxyge
cleavage单分子酸催化酰氧断裂baseacylBimolecularbasecatalyzedacyloxyge
cleavage双分子碱催化酰氧断裂acidU
imolecularacidcatalyzedalkyloxyge
cleavage单分子酸催化烷氧断裂basealBimllecularbasecatalyzedalkylyloxyge
cleavage双分子碱催化烷氧断裂complexπallylcomplexmecha
ismπ烯
丙型络合机理Borderli
emecha
ism边理机理Homolysis均裂Heterolysis异裂Heterolyticmicha
ism异裂机理Cou
rergege
io
反荷离子Io
par