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反应快。5、分别生成:3苯基2丁醇和2甲基戊醇6、只给出主要产物
11
f(1)CH3CHCCH322CH32CCHCH2OH
3C6H5CHCHCH3
4C6H5CHCHCHCH325CH3CHCCH3CCH3CHCH37、(1)对甲基苄醇>苄醇>对硝基苄醇
(2)α苯基乙醇>苄醇>β苯基乙醇
8、提示:在反应过程中,形成烯丙基正离子,因而生成两种产物。
9、略
10、(反应式略)
(1)CH3CH2CH2MgBrCH3CHO或CH3MgBrCH3CH2CH2CHO
(2)CH3MgBrCH3COCH2CH3或CH3CH2MgBrCH3COCH3
(3)CH3CH2MgBrC6H5CHO或C6H5MgBrCH3CH2CHO
(4)CH3MgBrC6H5COCH3或C6H5MgBrCH3COCH3
11、1
O
CH3OH
HCHO
CH3CHOHCH2CH3PBr3
HCHO干醚
CH3CHCH2CH3CH2OMgBr
CH3CHBrCH2CH3
Mg干醚

H3OCH3CHCH2CH3
CH2OH
CH3CHCH2CH3MgBr
2CH3CH2CH2OHCH2CHOHCH3
PBr3
Mg干醚
CH3CH2CH2MgBr
O
CH3COCH3
CH3CH2CH2MgBr干醚

H3O
CH3H3CCH2CH2CH3
OH
CH3
H3C
CH2CH2CH3
OMgBr
3HCHOCH3CH2MgBr干醚

H3OCH3CH2CH2OH
CH3CHOCH3MgBr干醚

H3O
CH3CHOHCH3
4CH32CHOHPBr3
Mg干醚
CH32CHMgBr
CH32CHCH2OHO
CH32CHCHO
CH32CHMgBr干醚
CH32CHCHCHCH32OMgBr

H3O
CH32CHCHCHCH32OH
H△H2O
CH32CHCHCCH32
(5)①Cl2,500℃②H2O,NaOH③HOCl④H2O,NaOH⑤3HNO3
12
f6CH3CHCH2水合
氧化
CH2CH2AlCl3
CH3COCH3CH2CH3H2
催化
CHCH2
HBrROOR
CH2CH2Br
Mg干醚
CH2CH2MgBrCH3COCH3
干醚

H3O
CH2CH2COHCH32

H

H2O
CH2CHCCH32
12、只给出提示(反应式略):(1)①H2O②HCl(2)①H2O②直接或间接水合
(3)①H2O②HBr③KOH醇13、只给出提示(反应式略):(1)①PBr3②Mg干醚③环氧乙烷④H2O(2)①CH3CH2CH2Mg,干醚②H3O③H2OH,△④硼氢化氧化(3)①C2H5ClAlCl3②NaOH③CH3I④CH3CH2CH2COClAlCl3⑤LiAlH4(4)选1,3丁二烯和3丁烯2酮①双烯合成②CH3Mg③H3O④H2Ni14、该醇的结构式为:CH32CHCHOHCH315、原化合物的结构式为CH3CHOHCH2CH3或CH3CH2CH2CH2OH(反应式略)16、A:CH32CHCHBrCH3B:CH32CHCHOHCH3C:CH32CCHCH3(反应式略)
CH3
17、H3C
CH2OH
CH3

HH2O
CH3
H3C
CH2重排
CH3
H3CCCH2CH3CH3

H
H3CCCHCH3
①O3
H3CCOCH3CHO
CH3
②Z
H2O
CH3
18、A:CH3CH2CHBrCHCH32B:CH3CH2CHCCH32
D:CH3CH2CHO
E:CH3COCH3
(各步反应式略)
C:CH3CHCHCHCH32
19、(1)CH3OCH2CH2CH3甲丙醚(甲氧基丙烷)C2H5OC2H5乙醚(乙氧基乙烷)CH3OCHCH32甲异丙醚(2甲氧基丙烷)
(2)CH3OCH2CH2CH2CH3甲丁醚(甲氧基丁烷)CH3OCHCH3CH2CH3甲仲丁醚(2甲氧基丁烷)
CH3OCH2CHCH32甲异丁醚(1甲氧基2甲基丙烷)CH3OCCH33甲叔丁醚2甲氧基2甲基丙烷
CH3CH2OCH2CH2CH3乙丙r
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