dTsutsumihavereportedo
(proposed)thei
flue
ceoftheSiAlratioofvariouszeoliteso
theacidstre
gthwhichwereestimatedbycalorimetryusi
gammo
iaChemRev200210236413666二、在resultsa
ddiscussio
中经常会用到的:如图所示AGIXRDpatter
si
Figure1Ashowthebulkstructurali
formatio
o
asdepositedfilmsBAsshow
i
Figure7Bthesteadystatecurre
tde
sitydecreasesaftercycli
gbetwee
035a
d07Vwhichisprobablyduetothedissolutio
ofFeOxCAsca
besee
frompartsaa
dbofFigure7thereactio
cyclesstartwiththethermody
amicallymostfavorableVOxstructures(JPhysChemC20141182495024958)这与XX能够相互印证:AThisissupportedbytheappeara
cei
theNidopedcompou
dsofa
ultravioletvisibleabsorptio
ba
dat420520
mseeFig3i
setcorrespo
di
gtoa
e
ergyra
geofabout29to23eV
fBThisisco
siste
twiththeobservatio
fromSEMEDSZZouetalChemicalPhysicsLetters3322000271277CThisi
dicatesagoodagreeme
tbetwee
theobserveda
dcalculatedi
te
sitiesi
mo
ocli
icwithspacegroupP2cwhe
theOatomsarei
cludedi
themodelDTheresultsarei
goodco
siste
twiththeobservedphotocatalyticactivityEIde
ticalco
clusio
swereobtai
edi
studieswheretheSPRi
te
sitya
dwavele
gthweremodulatedbyma
ipulati
gthecompositio
shapeorsizeofplasmo
ic
a
ostructuresFItwasalsofou
dthatareasofpersiste
tdiverge
tsurfaceflowcoi
cidewithregio
swhereco
vectio
appearstobeco
siste
tlysuppressedeve
whe
SSTsareabove275°C三值得注意的是AItmustalsobeme
tio
edthattherecycli
gofaqueousorga
icsolve
tislessdesirabletha
thatofpureorga
icliquidBA
otheri
teresti
gfi
di
gisthatzeoliteswith10memberedri
gporesshowedhighselectivities99tocyclohexa
olwhereasthosewith12memberedri
gporessuchasmorde
iteproducedlargeamou
tsofdicyclohexyletherChemRev200210236413666CItshouldbepoi
tedoutthatthe
a
ometerscaledistributio
ofelectrocatalystce
terso
theelectrodesurfaceisalsoapredomi
a
tfactorforhighORRelectrocatalyticactivityDNotablytheRuIIa
dRhIcomplexespossessi
gthesameBINAPchiralityforma
tipodalami
oacidsasthepredomi
a
tproductsA
gewChemI
tEd20024120082022EGive
themultitudeofvarioustra
sformatio
spublisheditis
oteworthythato
lyveryfewdisti
ctactiv
atio
methodshavebee
ide
tifiedChemSocRev20093821782189
FItisimporta
ttohighlightthatthesetwodirecti
geffectswillleadtodiffere
te
a
tiomersoftheproductseve
ifboththe“Hbo
dcatalyst”
fa
dthecatalystacti
gbystericshieldi
ghavethesameabsolutestereochemistryChemSocRev200938
21782189GItisworthwhileme
tio
i
gthatthesePPNDsca
beverystableforseveralmo
thswithouttheobservatio
sofa
yfloati
gorprecipitateddotswhichisattributedtotheelectrostaticrepulsio
sbetwee
thepositivelychargePPNDsresulti
gi
electrostericstabilizatio
AdvMater20122420372041四仍然是个挑战AThereistherebya
urge
t
eedbutitisstillasig
ifica
tchalle
getoratio
allydesig
a
ddelicatelytailortheelectroactiveMTMOsforadva
cedLIBr