2011年有机化学练习册英文测试题解答Comprehe
siveExerciseofOrga
icChemistryforChemi
istryStude
tsⅠNameeachofthefollowi
gcompou
dsclearlyshowi
gallaspectsofthestereochemistry
C2H5
1CH3CH2OCHCH322
Br
HCH2C＝C
CH3CHCHCOOHCl
3
H3CH
C
CHCH32CH2CH3
Ethylisopropylether
2chloro3methylpe
ta
oicacid3E6S6bromo3ethyl2methyl3hepte
e
4
CH3OH
5CH3CONCH32NNdimethyletha
amideNNdimethylacetamide
6
CH3
2methylspiro33hepta
e
omethylphe
ol
CHCH2
78
H3C
HH
HCl
9
C2H5NCH3
2ethylNmethylpirrole10CH3COCl
OOC－O－CCH2CH3－－
Be
zoicpropa
oica
hydride
R3chloro1pe
te
e
acetylchlorideetha
oylchroride
ⅡDrawstructuralformulasforeachofthefollowi
gcompou
dsclearlyshowi
gallaspectsofthestereochemistry125Dimethyl5ethylhepta
e222dimethyl3hexy
e
CH3CH3CHCH2CH2CCH2CH3CH3CH2CH3
31R2R1ethyl2methylcyclope
ta
e
CH3－CH3C－CC－CH2CH3－CH3
4βDglucopyra
oseco
former
CH3
CH2OHOHOHOOHOH
61chloro25diisopropylbicyclo2212hepte
e
CH2CH3
5Tetraethylammo
iumhydroxide
1
fCH2CH3CH3CH2NCH2CH3CH2CH3OH

ClCHCH32CH32CH
7
ohydroxybe
zaldehydeOCHHO
8
Lala
i
e
97R8S78epoxy2methyloctadeca
HCCH32CHCH23CH2OHCCH2CH28CH3
10R4methoxycyclohex2e
o
e
CH3OOH
ⅢChoosethebesta
swersforeachofthefollowi
gquestio
sSi
glechoiceo
lyo
echoiceiscorrectfor1701ForCH3CHCCH2poi
toutthehybridizatio
ofeachcarbo
fromlefttorightAsp3sp2sp2sp2Bsp3sp2spsp2Csp3sp2spspDsp3spspsp
2Whichofthefollowi
giselectrophilicreage
t？AHNO3BNaHSO3CH2N－NH2DHCN
3Whichofthefollowi
gis
ucleophilicreage
t？ABr2BNaHSO3CH2SO4DHCl
4Whichofthefollowi
gsubstitue
tsactivatesa
aromatic
ucleusACOOHBNO2COCH3DSO3H
5Whichofthefollowi
gdoes
otgivetheiodoformtest
AC6H5CHOBCH3COCH3CCH3CH2OHDCH3CC6H5O
6Whichofthefollowi
gstructuralformulashas
ogeometricalisomers
ACH3CHCHCH3BC6H5CHCHBrCClClClDClCl
7Whichofthefollowi
gisaromatic？
AOBCNH
D
8Whichofthefollowi
gletteredcarbo
carbo
bo
dsisthelo
gest？
aABCH3CH
b
CH2
cCCH3CCH
DCH3
d
CH3
2
f9Whichofthefollowi
gcarbocatio
sismoststable
ACH3CCH3BCH3CHCH3CCH3CH2DCH3
CHCH2
10Whichofthefollowi
gcompou
dsyieldsayellowoilwhe
treatedwith
itrousacid
ACH3CH2NH2BCH3CH22NHCCH3CH23NDNH2
11Whichofthefollowi
giseasiestwatersoluble
ACH2－CH－CH2OHOHOHBOHCECH3CHCH2CH2OHCH3
12Whichofthefollowi
gca
otreactwithsilver
itratetoproducesilverchlorideatordi
aryco
ditio
s
ACH3C－Cl－OBCH33C－Cl－CCH2CHCHCH3ClDCl
13Whicho
eca
otbeco
vertedi
toamidesbyr