t碱性溶剂Dielectricco
sta
t介电常数Solvatedelectro
溶剂化电子Acidbasecatalyzedreactio
酸碱催化反应Co
jugatebase共轭酸Co
jugatebase共轭碱Thermody
amicacidity热力学酸度Ki
eticacidity动力学酸度Electro
do
ofacceptorcomplexEDAcomplex电子给体受体络合物Host主体Guest客体Primaryisotopeeffect一级同位素效应Seco
daryisotopeeffect二级同位数效应I
verseisotopeeffect逆同位素效应Ki
eticco
trol动力学控制Thermody
amicco
trol热力学控制Substrate底物
5
fI
termediate中间体Reactivei
termediate活泼中间体Microscopicreversibility微观可逆性Hammo
dpostulate哈蒙德假说Li
earfreee
ergy线性自由能No
bo
dedi
teractio
非键相互作用Torsio
aleffect扭转效应Pitzerstrai
皮策张力Restrictedrotatio
阻碍旋转Eclipsi
geffect重叠效应Eclipsi
gstrai
重叠张力Smalla
glestrai
小角张力Largea
glestrai
大角张力Tra
sa
ulari
teractio
跨环相互作用Tra
sa
ularstrai
跨环张力Istrai
内张力Fstrai
前张力Bstrai
后张力A
omericeffect端基异构效应Walde
i
versio
瓦尔登反转Racemizatio
外消旋化Isoi
versio
等反转Isoracemizatio
等消旋Homochiral纯手性的Mecha
ism机理U
imolecular
ucleophilic单分子亲核取代Bimolecular
ucleophilicsubstitutio
双分子亲核取代Bimolecular
ucleophilicsubstitutio
withallylicrearra
geme
t双分子亲核取代（含烯丙型重排）I
ter
al
ucleophilicsubstirutio
分子内亲核取代Aromatic
ucleophilicsubstitutio
芳香亲核取代U
imolecularelectrophilicsubstitutio
单分子亲电取代Bimolecularelectrophilicsubstitutio
双分子亲电取代
6
Nucleophileassistedu
imolecularelectrophilicsubstitutio
亲核体协助单分子亲电取代U
imolecularelimi
atio
单分子消除Bimolecularelimi
atio
双分子消除U
imolecularelimi
atio
throughtheco
jugatebase单分子共轭碱消除Bimolecularelimi
atio
throughtheco
jugatebase双分子共轭碱消除Bimolecularelimi
atio
withformatio
ofacarbo
ylgroup双分子羰基形成消除U
imolecularacidcatalyzedacyloxyge
cleavage单分子酸催化酰氧断裂Bimolecularbasecatalyzedacyloxyge
cleavage双分子碱催化酰氧断裂U
imolecularacidcatalyzedalkyloxyge
cleavage单分子酸催化烷氧断裂Bimllecularbasecatalyzedalkyloxyge
cleavage双分子碱催化烷氧断裂πallylcomplexmecha
ismπ烯丙型络合机理Borderli
emecha
ism边理机理Homolysis均裂Heterolysis异裂Heterolyticmicha
ism异裂机理Cou
rergege
io
反荷离子Io
pair离子对Carbocatio
碳正离子No
classicalcarbocatio
非经典碳正离子Carba
io
碳负离子Maskedcarba
io
掩蔽碳负离子Carbe
oid卡宾体Carbe
e卡宾
fNitre
e氮宾Carbi
e碳炔Electrophilicadditio
亲电加成Electrophir