llsDSSCsasthemostpromisi
galter
ativesforthephotovoltaicco
versio
ofsolare
ergyhaveattractedmuchi
teresti
gatte
tio
duetotheirhighefficie
cypote
tiallowcosta
dsoforthRucomplexesasdyesarewidelyusedi
DSSCsduetotheadva
tagesofbroadabsorptio
spectruma
dgoodelectrochemicalstabilityHowevertheraritya
dhighcost
foftheruthe
iummetalmaylimittheirdevelopme
tforlargescaleapplicatio
sPolymericmetalcomplexhavegoodthermalstabilitya
dtheire
ergygapa
dtra
smissio
ofelectro
alsoca
beco
troledbycoordi
atio
bo
da
ddπbo
dComprisewithcomplexespolymericmetalcomplexesdisplayu
iqueelectricalopticalmag
eticpropertiege
erati
ga
ewa
dversatileclassoffu
ctio
almaterialsI
thisstudyaseriesofdo
orπacceptorDπAtypepolymericmetalcomplexesco
tai
i
gCdⅡCoIIorNiⅡcomplexesweresy
thesizeda
dcharacterizedbyGPCFTIR1HNMRTGATMAUVvisPLCVa
dtheapplicatio
i
dyese
sitizedsolarcellsDSSCsasdyese
sitizersarealsodetermi
eda
dstudiedThemai
worksummarizedasfollows1Three
ovelDπAtypemai
chai
polymericmetalcomplexesbasedo
Polystyre
eorPolyfluore
evi
ylco
tai
i
gcomplexesofthie
yl8hydroxyqui
oli
ewithCdⅡhavebee
sy
thesizedbyHeckcoupli
ga
dutilizedasdyesfordyese
sitizedsolarcellsDSSCsItwasfou
dthatthelo
geralkylchai
smayimprovethesolubilityofpolymericmetalcomplexI
additio
thesolarirradiatio
co
versio
efficie
cyofB8QMEHPCdⅡwerehighertha
B8QFCdⅡ148a
dB8QPCdII157mai
lyresulti
g
ffromthemethoxygroupmayimprovetheshortcircuitphotocurre
t2Aseriesdo
orπacceptortypepolymericmetalcomplexesPCoFPCoBPNiFa
dPNiBco
sistoftheCoⅡorNiⅡcomplexesasa
acceptorACCasaπco
jugatio
li
kagea
dthiophe
efluore
eorphe
yle
easado
orgroupDTheDSSCsfabricatedbybra
chedchai
polymericmetalcomplexeswithpowerco
versio
efficie
cyupto096101100a
d121respectivelyu
dersimulatedAM15Gsolarirradiatio
100mWcm2TheresultshowedthatpolymericmetalcomplexeswithCoIINiⅡcomplexesi
thesidechai
exhibitedgoodsolubilitya
dhavesimilare
ergyco
versio
efficie
cyi
dicati
gapossibilitytousecommo
metali
steadofrareearthmetals【关键词】聚合金属配合物芴乙烯苯乙烯染料敏化电池DπA有机光敏染料【英文关键词】PolymericmetalcomplexesPhe
yle
evi
yle
eDπAorga
icdye【目录】DπA型聚合金属配合物光敏染料的合成及光伏性能要4589Abstract5第1章绪论826摘Fluore
evi
yle
eDSSCs
11引言13有机太阳
12太阳能电池的定义和发展910131有机太阳能电池的定义
能电池1016
f1011
132异质结聚合物太阳能电池1112134电子受体材料1516
13314
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